Read e-book online Advances in Inorganic Chemistry, Vol. 52 PDF

By AG Sykes

ISBN-10: 0120236524

ISBN-13: 9780120236527

Advances in Inorganic Chemistry offers well timed and informative summaries of the present development in various topic components inside inorganic chemistry, starting from bioinorganic to reliable kingdom. This acclaimed serial beneficial properties experiences written through specialists within the sector and is an integral connection with complicated researchers. every one quantity of Advances in Inorganic Chemistry includes an index, and every bankruptcy is totally referenced.

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Reaction of 1,1-bis(N-methylimidazol-2-yl)-l-hydroxyethane(bimOH) with [Fe30(O2CMe)6(py)3](C104) in MeCN, followed by crystallization from CH2C12, gives [Fe602(OH)2(O2CMe)lo(bimO)2] (52) (130), where the hydroxy diimidazole ligand has displaced a terminal pyridine and a bridging carboxylate group from the original oxo-centered triangle, while two tt2-hydroxides and four 1,3-bridging carboxylates now bridge two triangles into a hexanuclear cage. A very similar cage, [Fe602(OH)2(O2CMe)lo(mimO)2] (53) (131), results i f 2-(N-methylimidazol-2-yl)-2-hydroxypropane(mimOH) is used in this reaction.

23, was first reported FIG. 23. The structure of [Fe8(O)2(OH)12(tacn)6]s+ (145). ) HIGH-NUCLEARITY 3d-METAL COMPLEXES 53 by Wieghardt and co-workers in 1984 (145). The cage was made by hydrolysis of[FeC13(tacn)] at pH 9 in the presence of bromide. The structure consists of a planar octanuclear iron core, bridged by two tt3-oxides and twelve t~2-hydroxides. The iron atoms can be considered to be a central {Fe402} butterfly capped on each edge by a further Fe(III) center. The six tacn ligands bind in a tridentate fashion to all the iron atoms except the two Fe(III) atoms at the body of the butterfly.

Lis first reported this structure in 1980 (14), but significant work on these cages dates from a report in 1988 by Christou, Hendrickson, and co-workers (115). In a recent paper, Yoo et al. list forty-six papers describing studies of these (Mn12} cages (116); this list is unlikely to be exhaustive. Given this level of interest, it is impossible to review all this work within a more general review; the following merely summarizes the major points of interest to chemists, without attempting to explain the controversial aspects of the quantum phenomena displayed by these extraordinary molecules.

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Advances in Inorganic Chemistry, Vol. 52 by AG Sykes

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